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Creators/Authors contains: "Alexander, C"

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  1. Siegel, Stephen F; Gopalakrishnan, Ganesh (Ed.)
    Scientific software is, by its very nature, complex. It is mathematical and highly optimized which makes it prone to subtle bugs not as easily detected by traditional testing. We outline how symbolic execution can be used to write tests similar to traditional unit tests while providing stronger verification guarantees and apply this methodology to a sparse matrix algorithm. 
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  2. Predicting the pace of acidification in the California Current System (CCS), a productive upwelling system that borders the west coast of North America, is complex because the anthropogenic contribution is intertwined with other natural sources. A central question is whether acidification in the CCS will follow the pace of increasing atmospheric CO2, or if climate effects and other biogeochemical processes will either amplify or attenuate acidification. Here, we apply the boron isotope pH proxy to cold-water orange cup corals to establish a historic level of acidification in the CCS and the Salish Sea, an associated marginal sea. Through a combination of complementary modeling and geochemical approaches, we show that the CCS and Salish Sea have experienced amplified acidification over the industrial era, driven by the interaction between anthropogenic CO2and a thermodynamic buffering effect. From this foundation, we project future acidification in the CCS under elevated CO2emissions. The projected change inpCO2over the 21stcentury will continue to outpace atmospheric CO2, posing challenges to marine ecosystems of biological, cultural, and economic importance. 
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  3. Abstract Understanding how microscopic structural domains govern macroscopic electronic properties is central to advancing hydride superconductors, yet such correlations remain poorly resolved under pressure. We report the synthesis and characterization of (La0.9Y0.1)H10superhydrides exhibiting coexisting cubic$${Fm}\bar{3}m$$ F m 3 ¯ m and hexagonal$$P{6}_{3}/{mmc}$$ P 6 3 / m m c clathrate phases observed over the pressure range from 168 GPa down to 136 GPa. Using synchrotron-based X-ray diffraction imaging at the upgraded Advanced Photon Source, we spatially resolved μm-scale distributions of these phases, revealing structural inhomogeneity across the sample. Four-probe resistance measurements confirmed superconductivity with two distinct transitions: an onset at 244 K associated with the cubic phase and a second near 220 K linked to the hexagonal phase. Notably, resistance profiles collected from multiple current and voltage permutations showed variations in transition width and onset temperature that correlated with the spatial phase distribution. These findings demonstrate a direct connection between local structural domains and superconducting behavior. 
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